Hetero Bi-Paddle-Wheel Coordination Networks: A New Synthetic Route to Rh-Containing Metal–Organic Frameworks
نویسندگان
چکیده
منابع مشابه
A new type of paddle-wheel coordination complex.
In the presence of Na(+) ions, the reaction of the ligand 2-hydroxy-1,3-bis-(3-oxo-3-(2-hydroxyphenyl)-propionyl)-benzene, H5L4, with M(AcO)2 salts (M = Mn, Co) gathers the conditions for the assembly of coordination complexes (NBu4)3[M2Na2(H2L4)3] (M = Mn(II) 1 and Co(II) 2), which exhibit a new paddle-wheel structure. The features of this new category of compounds are discussed as well as the...
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The reaction of Zn(NO3)2 x 6H2O, various dicarboxylic acids, and either 4,4'-bipyridine or N,N'-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain ch...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 2012
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.20110361